SYNTHESIS OF THE C(3)-C(15) SEGMENT OF RUTAMYCIN-B VIA A C(8)-C(9) FRAGMENT ASSEMBLY ALDOL REACTION - METAL DEPENDENCE OF THE ALDEHYDE AND ENOLATE DIASTEREOFACIAL SELECTIVITIES

被引：20

作者：

GUSTIN, DJ ^{[1
]}

VANNIEUWENHZE, MS ^{[1
]}

ROUSH, WR ^{[1
]}

机构：

[1] INDIANA UNIV,DEPT CHEM,BLOOMINGTON,IN 47405

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 20期

关键词：

D O I：

10.1016/0040-4039(95)00628-P

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The diastereofacial selectivities of aldehyde 2b and ketone 3 are metal dependent, and their fragment assembly aldol coupling is a matched double asymmetric reaction when a chlorortitanium enolate is used.

引用

页码：3447 / 3450

页数：4

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