Bis(acetato-kappa O-2, O')(4,4'-dimethyl-2,2'-bipyridine-kappa N-2, N') copper(II) monohydrate

被引:1
作者
Kaewthong, Aphiwat [1 ]
Sukwattanasinitt, Mongkol [1 ]
Muangsin, Nongnuj [2 ]
机构
[1] Chulalongkorn Univ, Fac Sci, Ctr Petr Petrochemicals & Adv Mat, Dept Chem, Bangkok 10330, Thailand
[2] Chulalongkorn Univ, Fac Sci, Res Ctr Bioorgan Chem, Dept Chem, Bangkok 10330, Thailand
关键词
D O I
10.1107/S1600536812020193
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Cu(C2H3O2)(2)(C12H12N2)(2)]center dot H2O, the Cu-II atom exhibits a distorted octahedral coordination geometry, defined by two N atoms from one 4,4'-dimethyl-2,2'- bipyridine ligand and four O atoms from two acetate ligands. In the crystal, O - H center dot center dot center dot O hydrogen bonds are observed between the coordinated carboxylate O atoms and the solvent water molecule.
引用
收藏
页码:M775 / +
页数:7
相关论文
共 10 条
[1]   Dibromido(4,4'-dimethyl-2,2'-bipyridine-κ2 N,N')zinc(II) [J].
Alizadeh, Robabeh ;
Eshlaghi, Parisa Mohammadi ;
Amani, Vahid .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 :M996-U1253
[2]   (6,6′-Dimethyl-2,2′-bipyridine-κ2N,N′)diiodidozinc(II) [J].
Alizadeh, Robabeh ;
Kalateh, Khadijeh ;
Khoshtarkib, Zeinab ;
Ahmadi, Roya ;
Amani, Vahid .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 :M1439-U1779
[3]   TABLES OF BOND LENGTHS DETERMINED BY X-RAY AND NEUTRON-DIFFRACTION .1. BOND LENGTHS IN ORGANIC-COMPOUNDS [J].
ALLEN, FH ;
KENNARD, O ;
WATSON, DG ;
BRAMMER, L ;
ORPEN, AG ;
TAYLOR, R .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1987, (12) :S1-S19
[4]   Synthesis, characterization and crystal structure determination of iron(III) complexes containing 4,4'-dimethyl-2,2'-bipyridine, dimethyl sulfoxide and chloride, [Fe(dmbipy)Cl4][dmbipyH] and [Fe(dmbipy)Cl3(DMSO)] [J].
Amani, Vahid ;
Safari, Nasser ;
Notash, Behrouz ;
Khavasi, Hamid Reza .
JOURNAL OF COORDINATION CHEMISTRY, 2009, 62 (12) :1939-1950
[5]  
Bruker, 2008, APEX2 SAINT SADABS
[6]  
Farrugia L.J., 1997, J APPL CRYSTALLOGR, V30, P565, DOI [DOI 10.1107/S0021889897003117, 10.1107/S0021889897003117]
[7]   Tetrachlorido(4,4′-dimethyl-2,2′-bipyri-dine-κ2N,N′)platinum(IV) [J].
Kashani, Leila Hojjat ;
Amani, Vahid ;
Yousefi, Mohammad ;
Khavasi, Hamid Reza .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 :M905-U471
[8]   A short history of SHELX [J].
Sheldrick, George M. .
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122
[9]   publCIF: software for editing, validating and formatting crystallographic information files [J].
Westrip, Simon P. .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2010, 43 :920-925
[10]   Crystal chemistry of the 4,4′-dimethyl-2,2′bipyridine/copper bromide system [J].
Willett, RD ;
Pon, G ;
Nagy, C .
INORGANIC CHEMISTRY, 2001, 40 (17) :4342-4352