ELECTRONIC ABSORPTION-SPECTRUM OF METHYL NITRITE IN THE NEAR-ULTRAVIOLET

被引：13
|
作者：
HIPPLER, M [1 ]
PFAB, J [1 ]
机构：
[1] HERIOT WATT UNIV,DEPT CHEM,EDINBURGH EH14 4AS,MIDLOTHIAN,SCOTLAND
来源：
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1992年 / 88卷 / 14期
关键词：
D O I：
10.1039/ft9928802109
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A re-examination of the structured near-UV electronic absorption spectrum of gaseous CH3ONO has revealed that previous assignments of the vibronic origin and of the prominent progression in the excited-state N=O stretching vibration are insecure. An alternative assignment that is in better agreement with the observed spectra and their temperature dependence is presented.
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页码：2109 / 2110
页数：2
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