CRYSTAL-STRUCTURE OF [1,8-BIS(QUINOLINIUMOXY)-3,6-DIOXAOCTANE.(H2O)2](BF4)2 - HYDRATED QUINOLINIUM PODAND SALT OR HYDRONIUM ION COMPLEX

被引：3

作者：

ARCHER, SJ ^{[1
]}

KOCH, KR ^{[1
]}

SACHT, C ^{[1
]}

机构：

[1] UNIV CAPE TOWN,DEPT CHEM,PRIVATE BAG RONDEBOSCH,RONDEBOSCH 7700,SOUTH AFRICA

来源：

INORGANICA CHIMICA ACTA | 1990年 / 178卷 / 01期

关键词：

D O I：

10.1016/S0020-1693(00)88137-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Structure of diprotonated, hydrated podand cation or hydronium ion complex? The title compound 2 represents the first example of a possible hydronium ion complex with an acyclic bis(quinolyl)-terminated oligoether. The molecule assumes a helical conformation, stabilized, in addition to intra-and intermolecular base stacking interactions, by two sets of bridging hydrogen bonds. The latter cannot unequivocally be formulated as either N...H-OH2+ or N-H+...OH2.

引用

页码：77 / 81

页数：5

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