DIMETHYLDIOXIRANE EPOXIDATION OF ENOL PHOSPHATES

被引：19
|
作者：
ADAM, W
HADJIARAPOGLOU, L
KLICIC, J
机构：
[1] Institute of Organic Chemistry, University of Würzburg, D-8700 Würzburg, Am Hubland
来源：
TETRAHEDRON LETTERS | 1990年 / 31卷 / 45期
关键词：
D O I：
10.1016/S0040-4039(00)97105-3
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The novel epoxides 2 of a variety of enol phosphates 1 were readily prepared by epoxidation with dimethyldioxirane at subambient temperatures; at room temperature these labile epoxides 2 rearranged into the corresponding α-dialkoxyphosphinyloxy-substituted carbonyl products 3. © 1990.
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页码：6517 / 6520
页数：4
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