SYNTHESIS OF BIS(N-METHYLIMIDAZOL-2-YL)KETONE (BIK) AND CRYSTAL-STRUCTURE OF [ZN(BIK)(2)](CLO4)(2)

被引：21
作者：
CHEN, XM [1 ]
XU, ZT [1 ]
MAK, TCW [1 ]
机构：
[1] CHINESE UNIV HONG KONG,DEPT CHEM,SHA TIN,HONG KONG
来源：
POLYHEDRON | 1995年 / 14卷 / 02期
关键词：
D O I：
10.1016/0277-5387(94)00340-K
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel polyimidazole ligand bis(N-methylimidazol-2-yl)ketone (BIK) has been synthesized and its first metal complex [Zn(BIK)(2)](ClO4)(2) has been structurally established by X-ray crystallography. The zinc atom is coordinated by two chelating BIK ligands in a distorted tetrahedral N-4 environment with Zn-N bonds at 1.997(8) Angstrom and N-Zn-N bond angles at 93.5(5)-137.3(5)degrees.
引用
收藏
页码：319 / 322
页数：4
相关论文
共 12 条
  • [1] AN L(3)ZNOH COMPLEX AS A FUNCTIONAL-MODEL OF THE ENZYME CARBONIC-ANHYDRASE
    ALSFASSER, R
    RUF, M
    TROFIMENKO, S
    VAHRENKAMP, H
    [J]. CHEMISCHE BERICHTE-RECUEIL, 1993, 126 (03): : 703 - 710
  • [2] ARMSTRONG WH, 1988, METAL CLUSTERS PROTE, P1
  • [3] MODELS FOR IRON OXO PROTEINS - STRUCTURES AND PROPERTIES OF FEIIFEIII, ZNIIFEIII, AND FEIIGAIII COMPLEXES WITH (MU-PHENOXO)BIS(MU-CARBOXYLATO)DIMETAL CORES
    BOROVIK, AS
    PAPAEFTHYMIOU, V
    TAYLOR, LF
    ANDERSON, OP
    QUE, L
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (16) : 6183 - 6195
  • [4] THE CHEMISTRY OF 1,4,7-TRIAZACYCLONONANE AND RELATED TRIDENTATE MACROCYCLIC-COMPOUNDS
    CHAUDHURI, P
    WIEGHARDT, K
    [J]. PROGRESS IN INORGANIC CHEMISTRY, 1987, 35 : 329 - 436
  • [5] THE EMERGENCE OF TRINUCLEAR CONSTELLATIONS AT METALLOBIOSITES
    FENTON, DE
    OKAWA, H
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (09): : 1349 - 1357
  • [6] SPIN EXCHANGE COUPLING IN ASYMMETRIC HETERODINUCLEAR COMPLEXES CONTAINING THE MU-OXO-BIS(MU-ACETATO)DIMETAL CORE
    HOTZELMANN, R
    WIEGHARDT, K
    FLORKE, U
    HAUPT, HJ
    WEATHERBURN, DC
    BONVOISIN, J
    BLONDIN, G
    GIRERD, JJ
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (05) : 1681 - 1696
  • [7] KADERA M, 1993, INORG CHIM ACTA, V214, P97
  • [8] SYNTHESIS AND CHARACTERIZATION OF DINUCLEAR COPPER(II) COMPLEXES OF THE DINUCLEATING LIGAND 2,6-BIS[(BIS((1-METHYLIMIDAZOL-2-YL)METHYL)AMINO)METHYL]-4-METHYLPHENOL
    OBERHAUSEN, KJ
    RICHARDSON, JF
    BUCHANAN, RM
    MCCUSKER, JK
    HENDRICKSON, DN
    LATOUR, JM
    [J]. INORGANIC CHEMISTRY, 1991, 30 (06) : 1357 - 1365
  • [9] SYNTHESIS AND CHARACTERIZATION OF TRINUCLEAR IRON(II) AND MANGANESE(II) CARBOXYLATE COMPLEXES - STRUCTURAL TRENDS IN LOW VALENT IRON AND MANGANESE CARBOXYLATES
    RARDIN, RL
    POGANIUCH, P
    BINO, A
    GOLDBERG, DP
    TOLMAN, WB
    LIU, SC
    LIPPARD, SJ
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (13) : 5240 - 5249
  • [10] SHELDRICK GM, 1990, SHELXTL PC PROGRAM P
12