HIGHLY DIASTEREOSELECTIVE DIELS-ALDER REACTION MEDIATED BY A CHIRAL AUXILIARY DERIVED FROM AMINO INDANOL - THE ROLE OF CONFORMATION ON DIASTEREOSELECTIVITY

被引：50

作者：

DAVIES, IW ^{[1
]}

SENANAYAKE, CH ^{[1
]}

CASTONGUAY, L ^{[1
]}

LARSEN, RD ^{[1
]}

VERHOEVEN, TR ^{[1
]}

REIDER, PJ ^{[1
]}

机构：

[1] MERCK & CO INC,RES LABS,DEPT MOLEC DESIGN & DIVERS,RAHWAY,NJ 07065

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 42期

关键词：

D O I：

10.1016/0040-4039(95)01584-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The oxazolidinone 2 derived from amino indanol 1 functions as a very efficient chiral auxiliary for the Diels-Alder reaction. The effect of conformation has been explored using a range of constrained phenyl glycinol analogues.

引用

页码：7619 / 7622

页数：4

共 11 条

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