ASYMMETRIC ALLYLATION OF ALDEHYDES WITH CHIRAL LEWIS-BASES

被引：246

作者：

DENMARK, SE

COE, DM

PRATT, NE

GRIEDEL, BD

机构：

[1] Roger Adams Laboratory, Department of Chemistry, University of Illinois, Urbana

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 21期

关键词：

D O I：

10.1021/jo00100a013

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The asymmetric allylation and crotylation of aromatic aldehydes with allylic trichlorosilanes can be promoted by chiral phosphoramides in high yield and modest enantiomeric excess. The reaction likely proceeds via a hexacoordinate siliconate species.

引用

页码：6161 / 6163

页数：3

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