ASYMMETRIC ALLYLATION OF ALDEHYDES WITH CHIRAL LEWIS-BASES

被引：248
作者：
DENMARK, SE
COE, DM
PRATT, NE
GRIEDEL, BD
机构：
[1] Roger Adams Laboratory, Department of Chemistry, University of Illinois, Urbana
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 21期
关键词：
D O I：
10.1021/jo00100a013
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The asymmetric allylation and crotylation of aromatic aldehydes with allylic trichlorosilanes can be promoted by chiral phosphoramides in high yield and modest enantiomeric excess. The reaction likely proceeds via a hexacoordinate siliconate species.
引用
收藏
页码：6161 / 6163
页数：3
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