ALLOYS OF PALLADIUM WITH METALS OF THE PLATINUM GROUP AS HYDROGEN-PERMEABLE MEMBRANE-COMPONENTS AT HIGH-TEMPERATURES OF GAS SEPARATION

被引:19
作者
BERSENEVA, FN
TIMOFEEV, NI
ZAKHAROV, AB
机构
[1] Institute of Machinery, Russian Academy of Sciences, Ural Branch, Ekaterinburg, 620219
[2] Ekaterinburg Non-Ferrous Metals Treatment Plant, Ekaterinburg
关键词
421 Strength of Building Materials; Mechanical Properties - 547.1 Precious Metals - 802.3 Chemical Operations - 804 Chemical Products Generally - 931.2 Physical Properties of Gases; Liquids and Solids;
D O I
10.1016/0360-3199(93)90097-T
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In order to choose alloys for high-temperature hydrogen diffusion membranes, a wide range of Pd alloys with Pt and Rh containing between 0 and 25% alloying addition have been studied. The effects of dissolved hydrogen on the phase composition and mechanical properties of Pd - Pt and Pd - Rh alloys were examined. Hydrogen diffusion, permeation and sticking coefficients for some of the binary and multicomponent Pd-based alloys have also been investigated. It is shown that multicomponent alloys of palladium with metals of the platinum group are considered to possibly be suitable membrane materials for a long service-life under conditions of high pressure and temperature.
引用
收藏
页码:15 / 18
页数:4
相关论文
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