CO2(CO)8-CATALYZED REACTION OF BENZYLIC ACETATES WITH HSIME3 AND CO - A NOVEL METHOD FOR HOMOLOGATION OF ALCOHOLS

被引：15

作者：

CHATANI, N ^{[1
]}

SANO, T ^{[1
]}

OHE, K ^{[1
]}

KAWASAKI, Y ^{[1
]}

MURAI, S ^{[1
]}

机构：

[1] OSAKA UNIV,FAC ENGN,DEPT APPL CHEM,SUITA,OSAKA 565,JAPAN

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 24期

关键词：

D O I：

10.1021/jo00311a001

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the presence of Co2(CO)8, the reaction of benzyl acetates with HSiMe3and carbon monoxide under mild reaction conditions (25 °C, 1 atm of CO) resulted in the incorporation of CO to give /3-phenethyl alcohols. The reaction is applicable to naphthyl-, furanyl-, thiophenyl-, and even ferrocenyl methyl acetates. © 1990, American Chemical Society. All rights reserved.

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页码：5923 / 5924

页数：2

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