STEREOSELECTIVITY IN OXIDATION OF SULPHOXIDES TO SULPHONES IN PRESENCE OF ASPERGILLUS NIGER

被引：33

作者：

AURET, BJ

BOYD, DR

HENBEST, HB

机构：

[1] Department of Chemistry, Queen's University

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1968年 / 18期

关键词：

D O I：

10.1039/j39680002374

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Sulphones can be formed when sulphoxides are kept with a growing culture of Aspergillus niger. Partial oxidation of some racemic sulphoxides gives recovered sulphoxides that are optically active. In one case where this is possible, an optically active sulphone is also produced.

引用

页码：2374 / &