ORGANOELEMENT DERIVATIVES OF 2-PYRONES AND ITS APPLICATION IN ORGANIC-SYNTHESIS

被引：0
|
作者：
KALININ, VN
SHILOVA, OS
机构：
来源：
USPEKHI KHIMII | 1994年 / 63卷 / 08期
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D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The methods of synthesis of 2-pyrones organometal (Li, Cu) and organoelement (Si, N, S) sigma-derivatives and 2-pyrones eta4-irontricarbonyl complexes and reactivity of these compounds are considered. The Diels-Alder reactions of organoelement 2-pyrone derivatives with dienophyles proceed in mild conditions stereoselectively. It develops the new synthetic pathway to polyfunctionalized cyclohexenes and cyclohexadienes.
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页码：693 / 699
页数：7
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