Electrolyte Conductivity of Salts in Hexamethylphosphotriamide

被引：49

作者：

Hanna, E. M.

Pethybridge, A. D. ^{[1
]}

Prue, J. E. ^{[1
]}

Spiers, D. J. ^{[1
]}

机构：

[1] Univ Reading, Dept Chem, Reading RG6 2AD, Berks, England

来源：

JOURNAL OF SOLUTION CHEMISTRY | 1974年 / 3卷 / 08期

关键词：

Electrolytic conductivity; alkali metal salts; hexamethylphosphotriamide; association;

D O I：

10.1007/BF00650401

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Precise conductivity measurements are reported for twenty-two 1:1 salts in hexamethylphosphotriamide at 25 degrees C. The results have been analyzed using the full versions of the equations of Fuoss-Hsia and of Pitts for the conductivity of the free ions. The K-A and Lambda(infinity) values are consistent with strong cation solvation but weak anion solvation by the solvent. Earlier results for salts in related solvents have been reanalyzed for comparative purposes.

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页码：563 / 583

页数：21

相关论文

共 28 条

[1] CONDUCTIBILITY OF A CERTAIN NUMBER OF ELECTROLYTES 1-1 IN DIMETHYLSULFOXIDE AND HEXAMETHYLPHOSPHOTRIAMIDE [J].

ATLANI, C ;

JUSTICE, JC ;

QUINTIN, M ;

DUBOIS, JE .

JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1969, 66 (01) :180-&

[2]

BARKER BJ, 1971, J AM CHEM SOC, V93, P1341

[3] CONDUCTOMETRIC BEHAVIOR OF ELECTROLYTES IN HEXAMETHYLPHOSPHOTRIAMIDE AT 25 DEGREES [J].

BRUNO, P ;

DELLAMON.M ;

RIGHETTI, E .

JOURNAL OF PHYSICAL CHEMISTRY, 1973, 77 (10) :1258-1261

[4] CONDUCTANCE OF ALKALI HALIDES .12. SODIUM AND POTASSIUM CHLORIDES IN WATER AT 25 DEGREES [J].

CHIU, YC ;

FUOSS, RM .

JOURNAL OF PHYSICAL CHEMISTRY, 1968, 72 (12) :4123-&

[5] PROPRIETES DIELECTRIQUES ET POLAIRES DE LHEXAMETAPOL [J].

DUBOIS, JE ;

VIELLARD, H .

JOURNAL DE CHIMIE PHYSIQUE, 1965, 62 (06) :699-&

[6] MOLAR CONDUCTIVITY OF SODIUM-FLUORIDE IN AQUEOUS-SOLUTION AT 25 DEGREES C - APPLICATIONS OF PITTS CONDUCTIVITY EQUATION [J].

DUER, WC ;

ROBINSON, RA ;

BATES, RG .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1972, 68 :716-&

[7] CONDUCTANCE OF ELECTROLYTE SOLUTIONS . A MODIFIED EXPRESSION FOR ITS CONCENTRATION DEPENDENCE [J].

FERNANDEZPRINI, R .

TRANSACTIONS OF THE FARADAY SOCIETY, 1969, 65 (564P) :3311-+

[8] CONDUCTANCE MEASUREMENTS ON SOLUTIONS OF SALTS IN SULPHOLANE AND THEIR INTERPRETATION [J].

FERNANDEZPRINI, R ;

PRUE, JE .

TRANSACTIONS OF THE FARADAY SOCIETY, 1966, 62 (521P) :1257-+

[9] ELECTRICAL CONDUCTANCES OF ALKALI, ALKALINE-EARTH AND TETRAALKYLAMMONIUM PERCHLORATES IN HEXAMETHYLPHOSPHORAMIDE SOLUTIONS [J].

FUJINAGA, T ;

IZUTSU, K ;

SAKURA, S .

NIPPON KAGAKU KAISHI, 1973, (01) :191-192

[10] ASSOCIATION OF 1-1 SALTS IN WATER [J].

FUOSS, RM ;

HSIA, KL .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1967, 57 (06) :1550-&