Optically detected Cl-35 and Cl-37 hyperfine and nuclear quadrupole interactions in excited triplet states in zero field

被引:21
作者
Buckley, M. J. [1 ,2 ]
Harris, C. B. [2 ]
机构
[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
[2] Lawrence Radiat Lab, Inorg Mat Res Div, Berkeley, CA 94720 USA
关键词
D O I
10.1016/0009-2614(70)85006-0
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The zero field optical detection of the electron spin resonance and Cl ENDOR of 8-chloroquinoiine in its (3)(pi,pi*) state is reported. The observed data is interpreted in terms of a spin-hamiltonian which includes the N-14, Cl-35, and Cl-37 nuclear-electron hyperfine and nuclear quadrupole interactions. Values for these parameters are obtained for the excited triplet state.
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页码:205 / 213
页数:9
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