Removal of Fe (III) from Aqueous Solution Using Thiosalcylic Acid as an Efficient and Novel Adsorbent

被引：7

作者：

Abd-Elhamid, A. I. ^{[1
]}

Aly, H. F. ^{[2
]}

机构：

[1] City Sci Res & Technol Applicat, Composite & Nanomat Dept, Adv Technol & New Mat Res Inst, POB 21934, Srta, Egypt

[2] Atom Energy Author, Hot Labs Ctr, Nasr 13759, Egypt

来源：

EGYPTIAN JOURNAL OF CHEMISTRY | 2018年 / 61卷 / 04期

关键词：

Thiosalcylic acid; Fe (III); TSA-Fe; Dye;

D O I：

10.21608/EJCHEM.2018.3312.1280

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

THE REMOVAL of Fe (III) from aqueous solution using thiosalcylic acid (TSA) as adsorbent have been demonstrated in this work. TSA was Characterized by SEM, EDX, FTIR and XRD. Various factors affecting the removal include the contact time, initial concentration of ions, adsorbent dose, initial pH and temperature have been studied. The experimental data showed that, the removal percent of Fe (III) ion is increased by increasing contact time, adsorbent dose and pH values. The sorption reaction was found to obey a pseudo second-order rate model with q(e) = 275.78 mg g(-1). The sorption isotherms data fit Langmuir and Freundlich models. The waste solid from the adsorption process (thiosalcylic acid adsorbed Fe (TSA-Fe)) successful in removal of methylene blue (MB) and crystal violet (CV) dyes from binary system.

引用

页码：617 / 627

页数：11

共 36 条

[11] Kinetics and equilibrium studies of methylene blue adsorption by spent coffee grounds [J].

Franca, Adriana S. ;

Oliveira, Leandro S. ;

Ferreira, Mauro E. .

DESALINATION, 2009, 249 (01) :267-272

[12]

Freundlich H, 1906, Z PHYS CHEM-STOCH VE, V57, P385

[13] Synthesis and biological activity of platinum(II) and palladium(II) thiosalicylate complexes with mixed ancillary donor ligands [J].

Henderson, W ;

McCaffrey, LJ ;

Nicholson, BK .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (16) :2753-2760

[14] Synthesis and X-ray structures of triphenylphosphine-mercury(II) thiosalicylate complexes: novel aggregation processes [J].

Henderson, W ;

Nicholson, BK .

INORGANICA CHIMICA ACTA, 2004, 357 (08) :2231-2236

[15] The sorption of lead(II) ions on peat [J].

Ho, YS ;

McKay, G .

WATER RESEARCH, 1999, 33 (02) :578-584

[16] Trace level removal studies of Cr(III) from aqueous solution [J].

Ikram, M ;

Rauf, MA ;

Rauf, N .

JOURNAL OF TRACE AND MICROPROBE TECHNIQUES, 2002, 20 (01) :119-125

[17] ADSORPTION OF CD(II) AND PB(II) ON BENTONITE UNDER ESTUARINE AND SEAWATER CONDITIONS [J].

KOZAR, S ;

BILINSKI, H ;

BRANICA, M ;

SCHWUGER, MJ .

SCIENCE OF THE TOTAL ENVIRONMENT, 1992, 121 :203-216

[18] COMPLEX FORMATION BETWEEN COBALT AND THIOSALICYLIC ACID [J].

KUMAR, AN ;

NIGAM, HL ;

KATYAL, M .

JOURNAL FUR PRAKTISCHE CHEMIE-PRACTICAL APPLICATIONS AND APPLIED CHEMISTRY, 1966, 33 (3-4) :160-+

[19] Adsorption of dye from aqueous solution by cashew nut shell: Studies on equilibrium isotherm, kinetics and thermodynamics of interactions [J].

Kumar, P. Senthil ;

Ramalingam, S. ;

Senthamarai, C. ;

Niranjanaa, M. ;

Vijayalakshmi, P. ;

Sivanesan, S. .

DESALINATION, 2010, 261 (1-2) :52-60

[20]

Lagergren S., 1898, HANDLINGAR, V24, P1

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