HYDROLYTIC CLEAVAGE OF TRIS(TRIMETHYLSIYL)-DERIVATIVES OF PHOSPHORUS ARSENIC AND ANTIMONY

被引：56
作者：
BURGER, H
GOETZE, U
机构：
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1968年 / 12卷 / 03期
关键词：
D O I：
10.1016/S0022-328X(00)88698-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The cleavage of [(CH3)3Si]3M (M = P, As) by H2O, D2O, and CH3OH is a convenient method for the preparation of [(CH3)3Si]nMD(D)3-n compounds. The 1H NMR and the vibrational spectra suggest a pyramidal structure of all P, As, and Sb derivatives and do not support the presence of π interactions in the SiM bond. © 1968.
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页码：451 / &
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