CRYSTAL AND MOLECULAR STRUCTURE OF HEXAAQUOALUMINUM HEXACHLORORUTHENATE TETRAHYDRATE

被引：16
作者：
HOPKINS, TE
ZALKIN, A
TEMPLETO.DH
ADAMSON, MG
机构：
[1] Lawrence Radiation Laboratory, Department of Chemistry, Berkeley, California
来源：
INORGANIC CHEMISTRY | 1969年 / 8卷 / 11期
关键词：
D O I：
10.1021/ic50081a034
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
An X-ray diffraction study of a single crystal of Al(H2O)6RuCl6·4H2O showed that it is monoclinic with a = 10.492(5)Å, b = 11.415(5)Å, c = 7.069 (5) Å, β = 92.69 (2)°, Z = 2, and Dx = 2.045 g/cm3. The space group is P21/n. The ruthenium and aluminum ions are found to lie at the centers of slightly distorted octahedra of chlorines and water molecules, respectively. The hydrogen bond network connecting the octahedra is discussed. The average Ru-Cl and Al-O distances are found to be 2.375(5)and 1.880(4)Å. © 1969, American Chemical Society. All rights reserved.
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页码：2421 / &
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