INVESTIGATION INTO THE KINETICS OF SELENIUM(VI) REDUCTION USING HYDRIDE GENERATION ATOMIC FLUORESCENCE DETECTION

被引：27
作者：
HILL, SJ
PITTS, L
WORSFOLD, P
机构：
[1] Department of Environmental Sciences, University of Plymouth, Plymouth, PL4 8AA, Drake Circus
来源：
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY | 1995年 / 10卷 / 05期
关键词：
ACTIVATION ENERGY; SELENIUM; ATOMIC FLUORESCENCE SPECTROMETRY; HYDRIDE GENERATION; SELENIUM REDUCTION;
D O I：
10.1039/ja9951000409
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Utilizing the rapid response times that are possible with atomic fluorescence spectrometers, the activation energy for the reduction of selenium(VI) to selenium(IV) has been calculated and found to be 90.4 kJ mol(-1) using 6 mol l(-1) HCl. Results from the studies indicate that full reduction of selenium(VI) to selenium(IV) may be obtained in as short a time as 6 min at 70 degrees C.
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页码：409 / 411
页数：3
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