JAHN-TELLER CONFORMATIONS FOR A MIXED-VALENCY MULTIELECTRON DIMER CLUSTER

被引：0
|
作者：
GAMURAR, VY
TSUKERBLAT, BS
机构：
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 1991年 / 32卷 / 04期
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中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Jahn-Teller distortions are considered for a bioctahedral cluster formed by two transition-metal ions of d2-d3 type. The strongest interactions between the d electrons and the totally symmetric and tetragonal vibrations are incorporated. The doubly degenerate Jahn-Teller minimum corresponds to an equilibrium configuration with symmetry C2v. The nondegenerate Jahn-Teller state corresponds to a C4v nuclear configuration.
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页码：461 / 466
页数：6
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