TIME-RESOLVED RESONANCE RAMAN STUDY OF THE LOWEST (D-PI-STAR, 3CT) EXCITED-STATE OF TRIS(2,2'-BIPYRIDINE)RUTHENIUM(II)

被引：281
作者：
DALLINGER, RF [1 ]
WOODRUFF, WH [1 ]
机构：
[1] UNIV TEXAS,DEPT CHEM,AUSTIN,TX 78712
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1979年 / 101卷 / 15期
关键词：
D O I：
10.1021/ja00509a066
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We report the time-resolved resonance Raman (TR3) spectrum of tris(2,2'-bipyridine)ruthenium(Il) in its lowest electronically excited state, *Ru(bpy)32+. This is the first report of the vibrational spectrum of an optically generated excited state in fluid solution. Because of intensive recent investigations of the photophysics1 and photochemistry2 5 of Ru(bpy)32+, the potential of this complex in the conversion of light into chemical energy2, and the fundamental significance of vibrational spectroscopy of the electronically excited state, 6 our results and their attendant structural information content on *Ru(bpy)32+are of considerable interest. © 1979, American Chemical Society. All rights reserved.
引用
收藏
页码：4391 / 4393
页数：3
相关论文
共 13 条
[1]  
BENASSON R, 1976, J AM CHEM SOC, V98, P3722
[2]   RESONANCE RAMAN-SPECTRA AND EXCITATION PROFILES OF TRIS(ALPHA-DIIMINE) COMPLEXES OF IRON(II) [J].
CLARK, RJH ;
TURTLE, PC ;
STROMMEN, DP ;
STREUSAND, B ;
KINCAID, J ;
NAKAMOTO, K .
INORGANIC CHEMISTRY, 1977, 16 (01) :84-89
[3]   SPECTROSCOPIC INVESTIGATIONS OF EXCITED-STATES OF TRANSITION-METAL COMPLEXES [J].
CROSBY, GA .
ACCOUNTS OF CHEMICAL RESEARCH, 1975, 8 (07) :231-238
[4]   VIBRATIONAL SPECTROSCOPY OF THE ELECTRONICALLY EXCITED-STATE - PULSE RADIOLYSIS-TIME-RESOLVED RESONANCE RAMAN STUDY OF TRIPLET BETA-CAROTENE [J].
DALLINGER, RF ;
GUANCI, JJ ;
WOODRUFF, WH ;
RODGERS, MAJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (05) :1355-1357
[5]  
DALLINGER RF, APPL SPECTROSC
[6]   INFRARED-SPECTRA OF TRIS(2,2'-BIPYRIDYL) COMPLEXES OF CHROMIUM, VANADIUM AND TITANIUM WITH LOW FORMAL OXIDATION NUMBERS OF METAL [J].
KONIG, E ;
LINDNER, E .
SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY, 1972, A 28 (07) :1393-&
[7]   LUMINESCENCE OF TRIS(2,2'-BIPYRIDINE)RUTHENIUM(2) DICHLORIDE [J].
LYTLE, FE ;
HERCULES, DM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (02) :253-&
[8]   OPTICAL AND THERMAL ELECTRON-TRANSFER IN METAL-COMPLEXES [J].
MEYER, TJ .
ACCOUNTS OF CHEMICAL RESEARCH, 1978, 11 (03) :94-100
[9]  
SPIRO TG, 1979, COMMUNICATION
[10]  
SUTIN N, 1978, ADV CHEM SER, P1
12