MONTE-CARLO SIMULATION OF DIFFUSION-CONTROLLED RESPONSE FUNCTIONS AT 2D EXPERIMENTAL ROUGH ELECTRODES

被引：15
|
作者：
TRIGUEROS, PP [1 ]
MAS, F [1 ]
CLARET, J [1 ]
SAGUES, F [1 ]
GALCERAN, J [1 ]
PUY, J [1 ]
机构：
[1] UNIV POLITECN CATALUNYA,ESCOLA TECN SUPER ENGN AGR,E-25006 LLEIDA,SPAIN
来源：
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1993年 / 348卷 / 1-2期
关键词：
D O I：
10.1016/0022-0728(93)80134-4
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The theoretical models proposed for the study of electrode processes under diffusion control on rough surfaces are tested using quasi-two-dimensional experimental electrodes obtained by zinc electrodeposition. Exponents of a generalized scaling law similar to the classical Cottrell equation, which depend on the fractal dimension of the mass distribution measure of the electrode, are calculated using Monte Carlo simulation. The validity of the algorithms of the simulation has been tested previously on flat electrodes.
引用
收藏
页码：221 / 246
页数：26
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