RANDOM PI-CONJUGATED COPOLYMERS CONSTITUTED OF ELECTRON-DONATING THIOPHENE UNITS AND ELECTRON-ACCEPTING PYRIDINE UNITS

被引：26

作者：

YAMAMOTO, T ^{[1
]}

SHIMURA, M ^{[1
]}

OSAKADA, K ^{[1
]}

KUBOTA, K ^{[1
]}

机构：

[1] GUNMA UNIV, FAC ENGN, KIRYU, GUNMA 376, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 06期

关键词：

D O I：

10.1246/cl.1992.1003

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dehalogenation copolymerization of 2,5-dibromothiophene and 2,5-dibromopyridine with zero-valent nickel complex gives random copolymers with molecular weight of 5x10(4)-5x10(6). They show unique doping-undoping cycles which are accounted for by shift of lone pair electron of pyridine ring to p-doped thiophene ring.

引用

页码：1003 / 1004

页数：2

共 4 条

[1] LASER-LIGHT SCATTERING OF PBLG IN DMF
KUBOTA, K
CHU, B
[J]. BIOPOLYMERS, 1983, 22 (06) : 1461 - 1487
[2] NEW HETEROAROMATIC POLYMERS FOR 3RD-ORDER NONLINEAR OPTICS
KURIHARA, T
KAINO, T
ZHOU, ZH
KANBARA, T
YAMAMOTO, T
[J]. ELECTRONICS LETTERS, 1992, 28 (07) : 681 - 682
[3] NEW METHOD FOR THE PREPARATION OF POLY(2,5-THIENYLENE), POLY(P-PHENYLENE), AND RELATED POLYMERS
YAMAMOTO, T
MORITA, A
MARUYAMA, T
ZHOU, ZH
KANBARA, T
SANECHIKA, K
[J]. POLYMER JOURNAL, 1990, 22 (02) : 187 - 190
[4] UNIQUE OPTICAL AND ELECTROCHEMICAL PROPERTIES OF PI-CONJUGATED ELECTRICALLY CONDUCTING COPOLYMERS CONSISTING OF ELECTRON-WITHDRAWING PYRIDINE UNITS AND ELECTRON-DONATING THIOPHENE UNITS
ZHOU, ZH
MARUYAMA, T
KANBARA, T
IKEDA, T
ICHIMURA, K
YAMAMOTO, T
TOKUDA, K
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (17) : 1210 - 1212

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