SYNTHESIS AND CHARACTERIZATION OF TRANS-[CO(NH3)4(NH2CH3)L]3+ [L = (CH3)2SO OR (CH3)2NCHO] COMPLEXES

被引：1
作者：
SIENRA, B
MASSAFERRO, A
机构：
[1] Cátedra de Química Inorgánica, Facultad de Química, Montevideo, Av. General Flores 2124
来源：
POLYHEDRON | 1991年 / 10卷 / 17期
关键词：
D O I：
10.1016/S0277-5387(00)86035-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Trans-[Co(NH3)4(NH2CH3)(CH3)2SO]3+ and trans-[Co(NH3)4(NH2CH3)(CH3) NCHO]3+ ions are prepared by Ag+-induced solvolysis of trans-[Co(NH3)4(NH2 CH3)X]2+ (X = Cl or Br) complexes in dimethylsulphoxide or dimethylformamide. The complexes were characterized by electronic, IR and H-1 magnetic resonance spectroscopy. Both, dimethylsulphoxide and dimethylformamide are bonded through the oxygen atom. The trans-complexes obtained are not contaminated with the cis-isomers.
引用
收藏
页码：2075 / 2078
页数：4
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