SYNTHESIS AND CRYSTAL-STRUCTURE OF THE NEW NEAR-LINEAR RH2MO TRINUCLEAR COMPLEX [(ETA-5-C5H5)RH(MU-CO)-(MU-PH2PC5H4N)RH(CO)MO(CO)3(ETA-5-C5H5)]

被引：10

作者：

LOSCHIAVO, S

FARAONE, F

LANFRANCHI, M

TIRIPICCHIO, A

机构：

[1] UNIV MESSINA,DIPARTIMENTO CHIM INORGAN & STRUTTURA MOLEC,SALITA SPERONE 31,I-98166 MESSINA,ITALY

[2] UNIV PARMA,CNR,CTR STUDIO STRUTTURIST DIFFRATTOMETR,IST CHIM GEN & INORGAN,I-43100 PARMA,ITALY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 387卷 / 03期

关键词：

D O I：

10.1016/0022-328X(90)87183-E

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Addition of [Mo(η5-C5H5)(CO)3]Na to a solution of the complex [η5-C5H5)Rh(μ-CO)(μ-Ph2 PC5H4N)Rh(CO)Cl] (1) in THF results in the replacement of the terminal chloride by the anion [Mo(η5-C5H5)(CO)3]- , to give the near-linear trinuclear complex [(η5-C5H5)Rh(μ-CO)(μ-Ph2 PC5H4N)Rh(CO)Mo(CO)3(η5 -C5H5)] (3) in a good yield. The crystal structure of 3 has been determined by an X-ray diffraction study. © 1990.

引用

页码：357 / 363

页数：7

共 50 条

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[4] PREPARATION, STEREOISOMERISM, AND DYNAMIC PROPERTIES OF [(ETA-5-C5H5)2FE2(CO)2(MU-CO)(MU-SIXBUT)], [(ETA-5-C5H5)2FE2(CO)2(MU-CO)(MU-SICLBUT)], [(ETA-5-C5H5)2FE2(CO)2(MU-CO)(MU-SIBRBUT)], [(ETA-5-C5H5)2FE2(CO)2(MU-CO)(MU-SIIBUT)] [(ETA-5-C5H5)2FE2(CO)2(MU-CO)(MU-SIMEBUT)]
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[10] REACTION OF CYCLOPENTADIENE WITH (ALKYLIDYNE)TRIRUTHENIUM CLUSTERS - SYNTHESES OF RU3(MU-3-CPH)(MU-CO)2(CO)6(ETA-5-C5H5) AND (MU-H)2RU3(MU-3-CPH)(MU-CO)(CO)6(ETA-5-C5H5) - CRYSTAL-STRUCTURES OF RU3(MU-3-CPH)(MU-CO)2(CO)6(ETA-5-C5H5) AND RU3(MU-3-CPH)(MU-CO)3(ETA-5-C5H5)3
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