Radiative lifetime of the NH3 center dot Hg(P-3(0)) complex

被引：0

作者：

Freeman, C. G. ^{[1
]}

McEwan, M. J. ^{[1
]}

Clahidge, R. F. C. ^{[1
]}

Phillips, L. F. ^{[1
]}

机构：

[1] Univ Canterbury, Dept Chem, Christchurch 1, New Zealand

来源：

CHEMICAL PHYSICS LETTERS | 1971年 / 9卷 / 06期

关键词：

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A lifetime of (1.86 +/- 0.08) x 10(-6) sec has been determined from phase-shift measurements of the luminescence emitted when the NH3 center dot Hg(P-3(0)) complex dissociates. The lifetime is independent of the ammoaia pressure. By allowing for the finite lifetime of the complex improved values of the rate constants for reaction of NH3 with Hg(P-3(0)) have been obtained.

引用

页码：578 / 580

页数：3

共 4 条

[1] Relaxation of Hg(6(3)P(0)) by NH3 in ternary collisions [J].

Callear, A. B. ;

Mcgurk, J. .

CHEMICAL PHYSICS LETTERS, 1970, 7 (05) :491-493

[2]

Freeman CG, 1971, CHEM PHYS LETT, V8, P226, DOI 10.1016/0009-2614(71)80021-0

[3] DECAY OF FLUORESCENCE [J].

METCALF, WS .

JOURNAL OF THE CHEMICAL SOCIETY, 1960, (OCT) :3726-3729

[4] MERCURY-SENSITIZED LUMINESCENCE OF NH3 AND ND3 [J].

NEWMAN, RH ;

FREEMAN, CG ;

MCEWAN, MJ ;

CLARIDGE, RF ;

PHILLIPS, LF .

TRANSACTIONS OF THE FARADAY SOCIETY, 1970, 66 (575) :2827-&

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