SYNTHESIS AND CHARACTERIZATION OF IRON(III) AND IRON(IV) COMPLEXES OF N-(2-HYDROXYPHENYL)SALICYLAMIDE AND HOMOLOGS

被引：17
作者：
KOIKAWA, M
OKAWA, H
MAEDA, Y
KIDA, S
机构：
[1] Department of Chemistry, Faculty of science, Kyushu University, Higashiku, Fukuoka, 812, Hakozaki
来源：
INORGANICA CHIMICA ACTA | 1992年 / 194卷 / 01期
关键词：
D O I：
10.1016/S0020-1693(00)85825-9
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The complexation of tridentate trianionic chelating ligands, N-(2-hydroxyphenyl)salicylamide (H3L1) and its homologs with a substituent on the 2-hydroxyphenyl moiety (5-CH3, H3L2; 5-Cl, H3L3), toward iron ion has been studied. The ligand H3L1 formed a high-spin iron(III) complex K3[Fe(L1)2] when treated with FeCl3 in an alkaline solution under open atmosphere. This complex was oxidized with Ce(IV) to a high-spin iron(IV) complex (NPr4)2[Fe(L1)2]. The ligand H3L2 formed a low-spin iron(IV) complex K2[Fe(L2)2] under open atmosphere, whereas the ligand H3L3 gave a high-spin iron(III) complex (PBu4)3[Fe(L3)2]. The complexes were characterized by means of cyclic voltammetry, electronic spectra and Mossbauer spectra.
引用
收藏
页码：75 / 79
页数：5
相关论文
共 50 条
  • [11] New organotin(IV) chlorides derived from N-(2-hydroxyphenyl)aryloxy sulfamates. Synthesis, characterization and DSC investigation
    Ali Akremi
    Adel Noubigh
    Journal of Chemical Sciences, 2019, 131
  • [12] Synthesis and characterization of iron(III) complexes of N-(2-thienylidene)-N'-isonicotinoylhydrazine, N-(2-furylidene)N'-salicyloylhydrazine and N-(2-thienylidene)-N'-salicyloylhydrazin
    Alaudeen, M
    Prabhakaran, CP
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1996, 35 (06): : 517 - 519
  • [13] Synthesis and structural characterization of the complexes of 2-alkoxycarbonylpropyltin trichlorides with hexamethylphosphoramide and N-(2-hydroxyphenyl)-2-hydroxy-1-naphthylaldimine
    Tian, LJ
    Zhou, ZY
    Zhao, B
    Sun, HT
    Yu, WT
    Yang, P
    SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 2000, 30 (02): : 307 - 317
  • [14] Synthesis and characterization of iron(II) and iron(III) porphyrin complexes
    Adeyemo, Adegboye O.
    Butts, Dannyelle
    Baker, Jannie
    Olubajo, Olarongbe
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2007, 233 : 196 - 196
  • [15] N-(2-hydroxyphenyl)-4-nitrophthalimide
    Mansor, Shahirah
    Zakaria, Norzalida
    Ariffin, Azhar
    Ng, Seik Weng
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O1770 - U2070
  • [16] MAGNETIC PROPERTIES OF SOME N-(2-HYDROXYPHENYL)-2-HYDROXY-1-NAPHTHYLMETHYLENEIMINATO-COMPLEXES OF OXOVANADIUM(IV) ION
    CARLISLE, GO
    CRUTCHFI.DA
    MCKNIGHT, MD
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1973, (16): : 1703 - 1705
  • [17] NICKEL(II) AND PALLADIUM(II) COMPLEXES OF N-(2-HYDROXYPHENYL)SALICYLAMIDES - SYNTHESIS, STRUCTURE, AND ELECTROCHEMICAL PROPERTIES
    KOIKAWA, M
    MAEDA, H
    OKAWA, H
    MATSUMOTO, N
    KIDA, S
    INAMOTO, K
    TOKII, T
    SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1995, 25 (09): : 1479 - 1491
  • [18] Synthesis and characterization of iron(II) and iron(III) complexes with a tridentate O,N,O′-ligand
    Enthaler, Stephan
    Someya, Chika I.
    Irran, Elisabeth
    INORGANIC CHEMISTRY COMMUNICATIONS, 2015, 52 : 56 - 59
  • [19] Synthesis, spectroscopic and structural studies on N-(2-hydroxyphenyl)cinnamaldimine and some bivalent metal complexes.
    De, Rajib Lal
    Mandal, Mahuya
    Roy, Lovely
    Mukherjee, Jaydeep
    Bhawal, Ruchika
    Maiti, Kamales
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2008, 47 (10): : 1480 - 1485
  • [20] N-ACETYLCYSTEINE COMPLEXES OF IRON(III) AND IRON(II) - SYNTHESIS, CHARACTERIZATION AND REACTION CHEMISTRY
    HAHN, JM
    BIGHAM, WS
    SHAPLEY, PA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1993, 206 : 24 - INOR
12345