MU-ETA-2-ETA-2-PEROXIDE IN BIOLOGICAL-SYSTEMS

被引：46

作者：

KITAJIMA, N

MOROOKA, Y

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1993年 / 18期

关键词：

D O I：

10.1039/dt9930002665

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A perspective on the synthesis, structure and reactivity of the mu-eta2:eta2-peroxo dinuclear copper(II) complexes [{Cu[HB(3,5-R2C3HN2)3]}2(O2)] (R = Me, Ph or Pr(i)) is presented. Their biological relevance to haemocyanin and tyrosinase that bind dioxygen as peroxide at the dinuclear copper site is demonstrated. The possibility of involvement of this particular co-ordination mode of peroxide in other biological systems is also discussed.

引用

页码：2665 / 2671

页数：7

共 47 条

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