ON THE MECHANISM OF THE SYNTHESIS OF ARYL CYCLOPROPANES FROM GAMMA-BENZENESULFONYLOXYALKYL SELENO AND TIN DERIVATIVES AND NORMAL-BUTYLLITHIUM

被引：29

作者：

KRIEF, A

HOBE, M

机构：

[1] Department of Chemistry, Facultés Universitaires Notre-Dame de la Paix, B-5000 Namur

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 43期

关键词：

D O I：

10.1016/S0040-4039(00)79034-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Gamma-Benzenesulfonyloxyalkyl selenides react with n-butyllithium and stereospecifically lead to aryl cyclopropanes with inversion of configuration at each of the reactive sites which is compatible with the "W mechanism."

引用

页码：6529 / 6532

页数：4

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