CHIRAL (ACYLOXY) BORANE CATALYZED ASYMMETRIC ALLYLATION OF ALDEHYDES

被引：0
|
作者：
FURUTA, K
MOURI, M
YAMAMOTO, H
机构：
来源：
SYNLETT | 1991年 / 08期
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D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Chiral (acyloxy)borane, obtained from (2R,3R)-2-O-(2,6-diisopropoxybenzoyl)tartaric acid and tetrahydrofuranborane complex, catalyzes the allylation of achiral aldehydes with allylsilanes to afford homoallylic alcohols with high enantiomeric excess. The reactions proceed in a catalytic manner.
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页码：561 / 562
页数：2
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