SOLVATION FORCES IN SIMPLE DENSE FLUIDS .1.

被引:277
作者
SNOOK, IK
VANMEGEN, W
机构
[1] Department of Applied Physics, Royal Melbourne Institute of Technology, Melbourne, Vic.
关键词
D O I
10.1063/1.439489
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The grand canonical ensemble Monte Carlo method is used to calculate the density profile of a simple dense liquid, under conditions close to the vapor line, between two solid bodies and also the solvation force between the solids due to the simple fluid. The force is large compared with the van der Waals force at moderate surface separations, h, but is an oscillatory function of h. At small values of h the solvation force is strongly repulsive. © 1980 American Institute of Physics.
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页码:2907 / 2913
页数:7
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