SOLVATION FORCES IN SIMPLE DENSE FLUIDS .1.

被引：278

作者：

SNOOK, IK

VANMEGEN, W

机构：

[1] Department of Applied Physics, Royal Melbourne Institute of Technology, Melbourne, Vic.

来源：

JOURNAL OF CHEMICAL PHYSICS | 1980年 / 72卷 / 05期

关键词：

D O I：

10.1063/1.439489

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The grand canonical ensemble Monte Carlo method is used to calculate the density profile of a simple dense liquid, under conditions close to the vapor line, between two solid bodies and also the solvation force between the solids due to the simple fluid. The force is large compared with the van der Waals force at moderate surface separations, h, but is an oscillatory function of h. At small values of h the solvation force is strongly repulsive. © 1980 American Institute of Physics.

引用

页码：2907 / 2913

页数：7

共 30 条

[1] INTERFACIAL DENSITY PROFILE OF A LENNARD-JONES FLUID IN CONTACT WITH A (100) LENNARD-JONES WALL AND ITS RELATIONSHIP TO IDEALIZED FLUID-WALL SYSTEMS - MONTE-CARLO SIMULATION [J].