Influence of the Amine Structure on the Combustion and Explosion of Vapor-Air Mixtures

被引：3

作者：

Akinin, N. I. ^{[1
]}

Raikova, V. M. ^{[1
]}

Khvostantseva, K. N. ^{[1
]}

机构：

[1] Mendeleev Russian Chem Technol Univ, Moscow, Russia

来源：

COKE AND CHEMISTRY | 2016年 / 59卷 / 12期

关键词：

aliphatic amines; vapor-air mixtures; flame propagation; concentration limits; enthalpy of combustion; combustion temperature; explosive temperature;

D O I：

10.3103/S1068364X16120036

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The enthalpy of formation and combustion is calculated for 15 aliphatic amines by various methods. These characteristics depend on the number of carbon atoms and the number of amino groups in the amine molecule. The combustion parameters are calculated when P = 1 atm and V = const, for mixtures of aliphatic amines with air. The adiabatic combustion temperature of mixtures of limiting composition is practically independent of the amine structure. The calculated values of the maximum pressure exceed 1000 kPa.

引用

页码：478 / 482

页数：5