NUCLEAR MAGNETIC-RELAXATION AND IONIC-CONDUCTIVITY IN LINASO4

被引：17
|
作者：
KANASHIRO, T [1 ]
YAMANISHI, T [1 ]
KISHIMOTO, Y [1 ]
OHNO, T [1 ]
MICHIHIRO, Y [1 ]
NOBUGAI, K [1 ]
机构：
[1] OSAKA UNIV,INST SCI & IND RES,IBARAKI,OSAKA 567,JAPAN
来源：
JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN | 1994年 / 63卷 / 09期
关键词：
SUPERIONIC CONDUCTOR; NUCLEAR RELAXATION RATE; VACANCY DIFFUSION; IONIC CONDUCTIVITY; ALKALI SULFATE;
D O I：
10.1143/JPSJ.63.3488
中图分类号：
O4 [物理学];
学科分类号：
0702 ;
摘要：
The temperature dependence of the spin-lattice relaxation time for Li-7 has been measured in a single crystal of LiNaSO4 over the temperature range of 450 K-770 K. The result can be explained by a mechanism of vacancy diffusion. The activation energies for the hopping of Li+ and Na+ vacancies are estimated to be E(1)=0.70 eV and E(2)=1.20 eV, respectively. In addition, the ionic conductivity has been measured as a function of frequency from 500 Hz to 20 MHz and the value of 1.59 eV is deduced as the activation energy, E(m) for the ionic diffusion in the extrinsic region. These values of E(1), E(2), E(m) are well compared with the corresponding values of 0.70 eV, 1.24 eV and the intermediate value between 1.74 eV for Li+ and 1.90 eV for Na+ ions evaluated from the previous NMR measurements.
引用
收藏
页码：3488 / 3493
页数：6
相关论文
共 50 条
  • [1] IONIC-CONDUCTIVITY OF SINGLE-CRYSTAL LINASO4
    MELLANDER, BE
    GRANELI, B
    ROOS, J
    SOLID STATE IONICS, 1990, 40-1 : 162 - 164
  • [2] Ionic conductivity and electrical relaxation study of polycrystalline LiNaSO4
    Ganesha, K. N.
    Govindaraj, G.
    INTERNATIONAL CONFERENCE ON MATERIALS SCIENCE AND TECHNOLOGY (ICMST 2012), 2015, 73
  • [3] Ionic conductivity and dielectric relaxation studies of LiNaSO4 single crystal
    Chen, R. H.
    Tseng, Chaw-Ming
    Shern, C. S.
    Fukami, T.
    SOLID STATE IONICS, 2010, 181 (19-20) : 877 - 882
  • [4] PROTON MAGNETIC-RELAXATION AND IONIC-CONDUCTIVITY OF AMMONIUM HYDRONIUM BETA''-ALUMINA
    FURUKAWA, Y
    NAKABAYASHI, Y
    KAWAI, S
    NAKAMURA, O
    SOLID STATE IONICS, 1982, 7 (03) : 219 - 223
  • [5] Nuclear magnetic resonance study of sulfate reorientations in LiNaSO4
    Shakhovoy, R. A.
    Rakhmatullin, A.
    Deschamps, M.
    Sarou-Kanian, V.
    Bessada, C.
    JOURNAL OF PHYSICS-CONDENSED MATTER, 2016, 28 (17)
  • [6] Synthesis, Characterization and Ion Conductivity Study of Nanocrystalline LiNaSO4
    Ganesha, K. N.
    Govindaraj, G.
    SOLID STATE PHYSICS, VOL 57, 2013, 1512 : 386 - 387
  • [7] NUCLEAR MAGNETIC-RELAXATION IN AGI IONIC SUPERCONDUCTOR
    BRINKMANN, D
    FREUDENREICH, W
    HELVETICA PHYSICA ACTA, 1977, 50 (05): : 593 - 593
  • [8] ELECTRICAL RELAXATION STUDIES OF LiNaSO4 USING A NEW ANOMALOUS RELAXATION FUNCTION
    Kumar, N. S. Krishna
    Ganesha, K. N.
    Govindaraj, G.
    Solid State Ionics: Ionics for Sustainable World, 2013, : 577 - 585
  • [9] High-temperature nuclear magnetic resonance study of phase transition kinetics in LiNaSO4
    Shakhovoy, R. A.
    Sarou-Kanian, V.
    Rakhmatullin, A.
    Veron, E.
    Bessada, C.
    JOURNAL OF APPLIED PHYSICS, 2015, 118 (24)
  • [10] DIFFERENCE BETWEEN NUCLEAR-SPIN RELAXATION AND IONIC-CONDUCTIVITY RELAXATION IN SUPERIONIC GLASSES
    NGAI, KL
    JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (08): : 6424 - 6430
12345