Crystal structure of (E)-5-benzyloxy-2{[(4-nitrophenyl) imino] methyl} phenol

被引:2
作者
Ghichi, Nadir [1 ]
Benaouida, Mohamed Amine [1 ]
Benboudiaf, Ali [1 ]
Merazig, Hocine [1 ]
机构
[1] Univ Constantine 1, Dept Chim, Fac Sci Exactes, Unite Rech Chim Environm & Mol Struct CHEMS, Constantine, Algeria
关键词
crystal structure; enol; imine; Schiff base; hydrogen bonding;
D O I
10.1107/S2056989015022173
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C20H16N2O4, the mol-ecule adopts an E conformation about the N=C bond. There is an intra-molecular O-H center dot center dot center dot N hydrogen bond forming an S(6) ring motif. The nitro-benzene and benz-yloxy rings are inclined to the central benzene ring by 4.34 (10) and 27.66 (11)degrees, respectively, and to one another by 31.40 (12)degrees. In the crystal, mol-ecules are linked via C-H O hydrogen bonds, forming zigzag chains along [001]. Within the chains there are C-H inter-actions present. The chains are linked via - interactions [inter-centroid distance = 3.7048 (15) angstrom], forming slabs parallel to the bc plane.
引用
收藏
页码:O1000 / U976
页数:9
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