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Crystal structure of (E)-5-benzyloxy-2{[(4-nitrophenyl) imino] methyl} phenol
被引:2
作者:
Ghichi, Nadir
[1
]
Benaouida, Mohamed Amine
[1
]
Benboudiaf, Ali
[1
]
Merazig, Hocine
[1
]
机构:
[1] Univ Constantine 1, Dept Chim, Fac Sci Exactes, Unite Rech Chim Environm & Mol Struct CHEMS, Constantine, Algeria
关键词:
crystal structure;
enol;
imine;
Schiff base;
hydrogen bonding;
D O I:
10.1107/S2056989015022173
中图分类号:
O7 [晶体学];
学科分类号:
0702 ;
070205 ;
0703 ;
080501 ;
摘要:
In the title compound, C20H16N2O4, the mol-ecule adopts an E conformation about the N=C bond. There is an intra-molecular O-H center dot center dot center dot N hydrogen bond forming an S(6) ring motif. The nitro-benzene and benz-yloxy rings are inclined to the central benzene ring by 4.34 (10) and 27.66 (11)degrees, respectively, and to one another by 31.40 (12)degrees. In the crystal, mol-ecules are linked via C-H O hydrogen bonds, forming zigzag chains along [001]. Within the chains there are C-H inter-actions present. The chains are linked via - interactions [inter-centroid distance = 3.7048 (15) angstrom], forming slabs parallel to the bc plane.
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页码:O1000 / U976
页数:9
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