Crystal structure of (E)-5-benzyloxy-2{[(4-nitrophenyl) imino] methyl} phenol

被引:2
|
作者
Ghichi, Nadir [1 ]
Benaouida, Mohamed Amine [1 ]
Benboudiaf, Ali [1 ]
Merazig, Hocine [1 ]
机构
[1] Univ Constantine 1, Dept Chim, Fac Sci Exactes, Unite Rech Chim Environm & Mol Struct CHEMS, Constantine, Algeria
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷
关键词
crystal structure; enol; imine; Schiff base; hydrogen bonding;
D O I
10.1107/S2056989015022173
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C20H16N2O4, the mol-ecule adopts an E conformation about the N=C bond. There is an intra-molecular O-H center dot center dot center dot N hydrogen bond forming an S(6) ring motif. The nitro-benzene and benz-yloxy rings are inclined to the central benzene ring by 4.34 (10) and 27.66 (11)degrees, respectively, and to one another by 31.40 (12)degrees. In the crystal, mol-ecules are linked via C-H O hydrogen bonds, forming zigzag chains along [001]. Within the chains there are C-H inter-actions present. The chains are linked via - interactions [inter-centroid distance = 3.7048 (15) angstrom], forming slabs parallel to the bc plane.
引用
收藏
页码:O1000 / U976
页数:9
相关论文
共 50 条
  • [1] Crystal structure of (E)-2-{[(4 -anilinophenyl)-imino]methyl}phenol
    Faizi, Md. Serajul Haque
    Iskenderov, Turganbay S.
    Sharkina, Natalia O.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : 28 - +
  • [2] Crystal structure of (E)-3-chloro-2-(((4-nitrophenyl)imino)methyl)phenol, C13H9ClN2O3
    Song, Wei
    Yang, Yanju
    Li, Jin
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2020, 235 (01): : 61 - 62
  • [3] (E)-2-Methyl-4-[(4-nitrophenyl)diazenyl]phenol dimethylformamide solvate
    Kosar, Basak
    Albayrak, Cigdem
    Guemruekcueoglu, Ismail
    Bueyuekguengoer, Orhan
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : O4772 - U5636
  • [4] Crystal structure, Hirshfeld surface analysis and DFT studies of (E)-4-methyl-2-{[(2-methyl-3-nitrophenyl)imino]methyl}phenol
    Cinar, Emine Berrin
    Faizi, Md Serajul Haque
    Yagci, Nermin Kahveci
    Dogan, Onur Erman
    Aydin, Alev Sema
    Agar, Erbil
    Dege, Necmi
    Mashrai, Ashraf
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2020, 76 : 1551 - +
  • [5] Crystal structure of (E)-5-diethylamino-2-({[4-(dimethylamino)phenyl]imino}-methyl)phenol
    Rani, C. Vidya
    Chakkaravarthi, G.
    Rajagopal, G.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : O503 - U419
  • [6] 2-{(E)-[(2-chloro-5-nitrophenyl) imino]methyl}-5-(diethylamino) phenol
    Butcher, Ray J.
    Jasinski, Jerry P.
    Yathirajan, H. S.
    Vijesh, A. M.
    Narayana, B.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : O3748 - U2475
  • [7] (E)-4-methoxy-2-[(4-nitrophenyl)iminomethyl]phenol
    Kosar, B
    Albayrak, Ç
    Odabasoglu, M
    Büyükgüngör, O
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O2106 - O2108
  • [8] 4-Chloro-2-[(E)-(4-nitrophenyl)diazenyl]phenol
    Aslanov, Leonid A.
    Paseshnichenko, Ksenia A.
    Yatsenko, Alexandr V.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O497 - U1589
  • [9] Crystal structure of (E)-2,6-dimethoxy-4-{[(4-methoxyphenyl)imino]methyl}phenol
    Faizi, Md Serajul Haque
    Lone, Mohamad Nadeem
    Dege, Necmi
    Malinkin, Sergey
    Sliva, Tatiana Yu
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2018, 74 : 1540 - +
  • [10] Crystal structures and antioxidant capacity of (E)-5-benzyloxy-2-{[(4-chlorophenyl)imino]methyl} phenol and (E)-5-benzyloxy-2-({[2-(1H-indol-3yl)ethyl]iminiumyl}methyl)phenolate
    Ghichi, Nadir
    Bensouici, Chawki
    Benboudiaf, Ali
    DJebli, Yacine
    Merazig, Hocine
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2018, 74 : 478 - +