RHODIUM MACROCYCLIC COMPLEXES - THE SYNTHESIS AND SINGLE-CRYSTAL X-RAY STRUCTURE OF [RH([18]ANEN2S4)](PF6)3.3H2O ([18]ANEN2S4=1,4,10,13-TETRATHIA-7,16-DIAZACYCLOOCTADECANE)

被引：8

作者：

BLAKE, AJ ^{[1
]}

REID, G ^{[1
]}

SCHRODER, M ^{[1
]}

机构：

[1] UNIV EDINBURGH,DEPT CHEM,W MAINS RD,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND

来源：

POLYHEDRON | 1990年 / 9卷 / 24期

关键词：

D O I：

10.1016/S0277-5387(00)84202-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of [Rh(H2O)6]3+ with one molar equivalent of [18]aneN2S4 in refluxing MeOH-H2O (1:L1 v/v) for 12 h affords an orange solution from which the complex [Rh([anesN2S4)](PF6)3 can be isolated upon addition of NH4PF6. A single crystal X-ray structure determination shows a distorted octahedral geometry at rhodium(III) involving the four thioether and two aza-donors of the macrocycle. The complex cation adopts a racconfiguration via meridional coordination of the two SCH2CH2NCH2CH2S linkages.

引用

页码：2925 / 2929

页数：5

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