ZINC MESO-TETRAPHENYLPORPHYRIN AS SHIFT-REAGENT FOR NADH-MODELS

被引：10

作者：

SKOG, K ^{[1
]}

WENNERSTROM, O ^{[1
]}

机构：

[1] CHALMERS UNIV TECHNOL,DEPT ORGAN CHEM,S-41296 GOTHENBURG,SWEDEN

来源：

TETRAHEDRON | 1994年 / 50卷 / 27期

关键词：

D O I：

10.1016/S0040-4020(01)85304-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

By the use of zinc meso-tetraphenylporphyrin as a shift reagent the conformations of two new NADH-models have been determined. Induced H-1-NMR shifts up to five ppm have been observed. The conformations determined in this study are consistent with theoretical calculations and NOE-measurements. It has been proven that zinc, which is a co-catalyst in the reduction of activated carbonyl compounds with NADH-models, coordinates to the oxygen of the amide groups in two of our model compounds.

引用

页码：8227 / 8236

页数：10

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