NMR DIFFERENTIATION OF ENANTIOMERIC (+)-ALPHA-PINENE AND (-)-ALPHA-PINENE VIA COMPLEXATION WITH CYCLODEXTRINS IN WATER

被引：40

作者：

BOTSI, A

YANNAKOPOULOU, K

HADJOUDIS, E

PERLY, B

机构：

[1] NCSR DEMOKRITOS,INST PHYS CHEM,GR-15310 ATHENS,GREECE

[2] CENS,CEA,SERV CHIM MOLEC,F-91191 GIF SUR YVETTE,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 13期

关键词：

D O I：

10.1039/c39930001085

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(+)- and (-)-alpha-Pinene form diastereoisomeric complexes with alpha-, 2,3,6-tri-O-methyl-alpha-, 2,3,6-tri-0-methyl-beta- and 2,3,6-tri-O-acetyl-beta-cyclodextrin which are distinguishable in H-1 and C-13 NMR spectra, the alpha-pinene protons obeying the slow exchange condition during the complexation process; utilization of cyclodextrins as chiral shift reagents for molecules lacking polar groups is consequently proposed.

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页码：1085 / 1086

页数：2

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