catena-Poly[[bis(dimethylformamide-kappa O)-cadmium]-bis(mu-4-nitrophenylcyanamido-kappa N-2(1):N-3)]

被引：3

作者：

Chiniforoshan, Hossein ^{[1
]}

Jazestani, Mehdi ^{[1
]}

Notash, Behrouz ^{[2
]}

机构：

[1] Isfahan Univ Technol, Dept Chem, Esfahan 8445638111, Iran

[2] Shahid Beheshti Univ, Dept Chem, Tehran 1983963113, Iran

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷

关键词：

data-to-parameter ratio = 19.4; mean σ(C-C) = 0.005 Å; R factor = 0.044; single-crystal X-ray study; T = 298 K; wR factor = 0.114;

D O I：

10.1107/S1600536812001924

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title coordination polymer, [Cd(C 7H 4N 3O 2) 2(C 3H 7NO) 2] n, the Cd II atom, lying on an inversion center, is six-coordinated in a distorted N 4O 2 octahedral geometry. The N atoms of the 4-nitrophenylcyanamide anions form the equatorial plane and the O atoms of the dimethylformamide molecules occupy the axial positions. The anions act as bridging ligands, connecting the Cd atoms into a one-dimensional coordination polymer along [100].

引用

页码：M232 / U306

页数：7

共 10 条

[1] SYNTHETIC, SPECTROSCOPIC AND X-RAY CRYSTALLOGRAPHIC STUDIES ON PHENYLCYANAMIDOCOPPER(I) COMPLEXES
AINSCOUGH, EW
BAKER, EN
BRADER, ML
BRODIE, AM
INGHAM, SL
WATERS, JM
HANNA, JV
HEALY, PC
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (05): : 1243 - 1249
[2] catena-Poly[[(dimethylformamide-κO)cobalt(II)]-bis[μ-(4-nitrophenyl)cyanamido]-κ2N1:N3;κ2N3:N1]
Chiniforoshan, Hossein
Shirinfar, Bahare
Jalilpour, Soghra
Khavasi, Hamid Reza
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M331 - U3835
[3] catena-Poly[[(dimethylformamide-κO)copper(II)]-bis(μ-4-nitrophenylcyanamido-κ2N1:N3)]
Chiniforoshan, Hossein
Jalilpour, Soghra
Shirinfar, Bahare
Khavasi, Hamid Reza
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M386 - U432
[4] Phenylcyanamide ligands and their metal complexes
Crutchley, RJ
[J]. COORDINATION CHEMISTRY REVIEWS, 2001, 219 : 125 - 155
[5] PENTAAMMINERUTHENIUM(III) COMPLEXES OF NEUTRAL AND ANIONIC (2,3-DICHLOROPHENYL)CYANAMIDE - SPECTROSCOPIC ANALYSIS OF LIGAND TO METAL CHARGE-TRANSFER SPECTRA
CRUTCHLEY, RJ
NAKLICKI, ML
[J]. INORGANIC CHEMISTRY, 1989, 28 (10) : 1955 - 1958
[6] New examples of the unusual X-phenylcyanamido bridging ligands.: Crystal structure and magnetic properties of MnII derivatives
Escuer, A
Mautner, FA
Sanz, N
Vicente, R
[J]. POLYHEDRON, 2004, 23 (08) : 1409 - 1417
[7] Farrugia L.J., 1997, J APPL CRYSTALLOGR, V30, P565, DOI [DOI 10.1107/S0021889897003117, 10.1107/S0021889897003117]
[8] Farrugia L.J., 1999, J APPL CRYSTALLOGR, V32, P837, DOI [10.1107/S0021889812029111, DOI 10.1107/S0021889812029111]
[9] A short history of SHELX
Sheldrick, George M.
[J]. ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 : 112 - 122
[10] Stoe & Cie, 2002, X AREA X RED32 X SHA

← 1 →