SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF TRANS-[MOF(CCH2TERT-BU)(PH2PCH2CH2PPH2)2][BF4], A PARAMAGNETIC ALKYLIDYNEFLUOROCOMPLEX

被引：0

作者：

LEMOS, MANDA

POMBEIRO, AJL

HUGHES, DL

RICHARDS, RL

机构：

[1] INST SUPER TECN,CTR QUIM ESTRUTURAL,COMPLEXO I,AV ROVISCO PAIS,P-1096 LISBON,PORTUGAL

[2] UNIV SUSSEX,AFRC IPSR NITROGEN FIXAT LAB,BRIGHTON BN1 9RQ,E SUSSEX,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 434卷 / 01期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of the alkynylhydridocomplex [MoH3(C=CtBu)(dppe)2](dppe = Ph2PCH2CH2PPh2) with [Et2OH][BF4] gives trans-[MoF(=CCH2tBu)(dppe)2], the first example of a stable paramagnetic alkylidyne complex, the X-ray structure of which is reported.

引用

页码：C6 / C9

页数：4

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