(VAPOR + LIQUID) EQUILIBRIA IN (PROPAN-1-OL + NORMAL-HEXANE + NORMAL-HEPTANE) AT THE TEMPERATURE 313.15-K

被引:26
作者
ZIELKIEWICZ, J
机构
[1] Technical University of Gdańsk, Institute of Inorganic Chemistry, Technology, and Corrosion, Department of Physical Chemistry, 80-952 Gdańsk
关键词
D O I
10.1016/S0021-9614(05)80103-X
中图分类号
O414.1 [热力学];
学科分类号
摘要
Measurements have been made of the vapour pressure for (propan-1-ol + n-hexane + n-heptane), and for the binary constituent mixtures, at the temperature 313.15 K. The binary results have been fitted to various equations, and the possibility of predictions of the ternary quantities from binary quantities is proved using the UNIQUAC, Wilson, and NRTL equations as the basis. Moreover, the ternary quantities are correlated by taking advantage of an empirical equation with adjusted ternary parameters. The results relating to (propan-1-ol + n-hexane) and (propan-1-ol + n-heptane) have been compared with values given in the literature. © 1991 Academic Press Limited All rights reserved.
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页码:605 / 612
页数:8
相关论文
共 21 条
[1]   STATISTICAL THERMODYNAMICS OF LIQUID-MIXTURES - NEW EXPRESSION FOR EXCESS GIBBS ENERGY OF PARTLY OR COMPLETELY MISCIBLE SYSTEMS [J].
ABRAMS, DS ;
PRAUSNITZ, JM .
AICHE JOURNAL, 1975, 21 (01) :116-128
[2]  
Acree W. E., 1984, THERMODYNAMICS PROPE
[3]  
Boublik T., 1984, VAPOUR PRESSURES PUR
[4]  
Brown I, 1969, J CHEM THERMODYN, V1, P273, DOI 10.1016/0021-9614(69)90047-0
[5]  
FU JS, 1966, J APPL CHEM LONDON, V16, P324
[6]  
Gmehling J., 1977, VAPOR LIQUID EQUILIB, V1
[7]   GENERALIZED METHOD FOR PREDICTING 2ND VIRIAL-COEFFICIENTS [J].
HAYDEN, JG ;
OCONNELL, JP .
INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT, 1975, 14 (03) :209-216
[8]   VAPOR-LIQUID-EQUILIBRIA AT 25-DEGREES-C FOR 9 ALCOHOL-HYDROCARBON BINARY-SYSTEMS [J].
HWANG, SC ;
ROBINSON, RL .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1977, 22 (03) :319-325
[9]  
JANASZEWSKI B, 1982, FLUID PHASE EQUILIBR, V9, P235
[10]   CALCULATION OF MULTICOMPONENT VAPOUR-LIQUID EQUILIBRIUM FROM LIQUID BOILING TEMPERATURE DATA [J].
JASINSKI, B ;
MALANOWS.S .
CHEMICAL ENGINEERING SCIENCE, 1970, 25 (06) :913-&