Significant improvements in CdTe/CdS solar cell efficiency are commonly observed as a result of a postdeposition CdCl2 dip followed by a 400-degrees-C heat treatment during cell processing which increases CdTe grain size. In this paper, we investigate the electronic mechanisms responsible for CdCl2-induced improvement in cell performance along with possible performance-limiting defects resulting from this process in molecular-beam epitaxy-grown polycrystalline CdTe/CdS solar cells. Current density-voltage-temperature (J-V-T) analysis revealed that the CdCl2 treatment changes the dominant current transport mechanism from interface recombination/tunneling to depletion region recombination, suggesting a decrease in the density and dominance of interface states due to the CdCl2 treatment. It is shown that the change in transport mechanism is associated with (a) an increase in heterojunction barrier height from 0.56 to 0.85 eV, (b) a decrease in dark leakage current from 4.7 X 10(-7) A/cm2 to 2.6 X 10(-9) A/cm2 and, (c) an increase in cell V(oc) from 385 to 720 mV. The CdCl2 also improved the optical response of the cell. Substantial increases in the surface photovoltage and quantum efficiency accompanied by a decrease in the bias dependence of the spectral response in the CdCl2-treated structures indicate that the CdCl2 treatment improves carrier collection from the bulk as well as across the heterointerface. However, deep level transient spectroscopy measurements detected a hole trap within the CdTe depletion region of the CdCl2-treated devices at E(v) + 0.64 eV which is attributed to the formation of V(Cd)-related defects during the annealing process after the CdCl2 dip. J-V-T analysis demonstrated that this trap is the probable source of dominant recombination in the CdCl2-treated cells. An inverse correlation was found between the density of the E(v) + 0.64 eV trap and cell V(oc), suggesting that the heat treatment with CdCl2 may eventually limit the CdTe/CdS cell performance unless the formation of this defect complex is controlled or eliminated.
