ARYNES VIA APROTIC DIAZOTIZATION OF ANTHRANILIC ACIDS

被引：138
作者：
FRIEDMAN, L
LOGULLO, FM
机构：
[1] Department of Chemistry, Case Western Reserve University, Cleveland
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 10期
关键词：
D O I：
10.1021/jo01262a065
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Aprotic diazotization of anthranilic acids generates the corresponding benzenediazonium-2-carboxylates which decompose in situ to give arynes, carbon dioxide, and nitrogen. Moderate to excellent yields of aryne-derived products are obtained when the reaction is conducted in the presence of suitable acceptors. © 1969, American Chemical Society. All rights reserved.
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页码：3089 / &
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