CALORIMETRIC STUDY OF THE GLASS-TRANSITION OCCURRING IN FRUCTOSE SOLUTIONS

被引：49

作者：

ABLETT, S ^{[1
]}

IZZARD, MJ ^{[1
]}

LILLFORD, PJ ^{[1
]}

ARVANITOYANNIS, I ^{[1
]}

BLANSHARD, JMV ^{[1
]}

机构：

[1] UNIV NOTTINGHAM,SCH AGR,DEPT APPL BIOCHEM & FOOD SCI,LOUGHBOROUGH LE12 5RD,LEICS,ENGLAND

来源：

CARBOHYDRATE RESEARCH | 1993年 / 246卷

关键词：

D O I：

10.1016/0008-6215(93)84020-7

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The glass transition temperatures for dilute and concentrated fructose-water solutions have been determined by differential scanning calorimetry. The supplemented phase diagram is presented, and from this, the glass transition temperature (T(g)') and concentration (C(g)') of the maximally freeze-concentrated glass have been determined and found to differ, significantly for the latter and slightly for the former, from recently published values. Reasons for this discrepancy are discussed. Annealing vitrified fructose-water glasses above their T(g) allows the fructose concentration in the amorphous phase to approach C(g)' as a result of ice formation.

引用

页码：13 / 22

页数：10

共 50 条

[1] CALORIMETRIC STUDY OF THE GLASS-TRANSITION OCCURRING IN AQUEOUS GLUCOSE - FRUCTOSE SOLUTIONS
ARVANITOYANNIS, I
BLANSHARD, JMV
ABLETT, S
IZZARD, MJ
LILLFORD, PJ
JOURNAL OF THE SCIENCE OF FOOD AND AGRICULTURE, 1993, 63 (02) : 177 - 188
[2] CALORIMETRIC STUDY OF GLASS-TRANSITION IN GELATIN
TSERETELI, GI
SMIRNOVA, OI
VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A, 1991, 33 (10): : 2250 - 2256
[3] A CALORIMETRIC STUDY OF THE GLASS-TRANSITION KINETICS IN POLYISOPRENE
BAKULE, R
BIROS, J
FAHNRICH, J
COLLOID AND POLYMER SCIENCE, 1991, 269 (07) : 665 - 674
[4] CALORIMETRIC MEASUREMENTS OF THE GLASS-TRANSITION
CLAVAGUERAMORA, MT
THERMOCHIMICA ACTA, 1989, 148 : 261 - 267
[5] CALORIMETRIC STUDY OF GLASS-TRANSITION OF BICOMPONENT POLYMER BLENDS
GODOVSKII, YK
BESSONOVA, NP
VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A, 1979, 21 (10): : 2293 - 2304
[6] A RHEOLOGICAL MODEL OF THE CALORIMETRIC GLASS-TRANSITION
FERRARI, L
RUSSO, G
JOURNAL OF PHYSICS-CONDENSED MATTER, 1993, 5 (31) : 5525 - 5542
[7] THE CALORIMETRIC GLASS-TRANSITION - A SIMPLE-MODEL
HUNT, A
PHILOSOPHICAL MAGAZINE B-PHYSICS OF CONDENSED MATTER STATISTICAL MECHANICS ELECTRONIC OPTICAL AND MAGNETIC PROPERTIES, 1991, 64 (05): : 563 - 577
[8] THE EFFECT OF FRUCTOSE AND WATER ON THE GLASS-TRANSITION OF AMYLOPECTIN
KALICHEVSKY, MT
BLANSHARD, JMV
CARBOHYDRATE POLYMERS, 1993, 20 (02) : 107 - 113
[9] A STUDY OF THE GLASS-TRANSITION IN POLYMERIC MESOPHASES VIA CALORIMETRIC AND NONLINEAR ESR TECHNIQUES
ANDREOZZI, L
GIORDANO, M
LEPORINI, D
MARTINELLI, M
PACI, M
ANGELONI, AS
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1992, 212 : 107 - &
[10] THE VISCOSITY OF SUPERCOOLED FRUCTOSE AND ITS GLASS-TRANSITION TEMPERATURE
OLLETT, AL
PARKER, R
JOURNAL OF TEXTURE STUDIES, 1990, 21 (03) : 355 - 362

← 1 2 3 4 5 →