Detection of Pb in Atmospheric Particulates with Laser-Induced Breakdown Spectroscopy Technique

被引:4
作者
Zhang Qihang [1 ]
Liu Yuzhu [1 ,2 ]
Zhu Ruosong [1 ]
Jin Feng [3 ]
Zhou Fengbin [1 ]
Yin Wenyi [1 ]
机构
[1] Nanjing Univ Informat Sci & Technol, Jiangsu Key Lab Optoelect Detect Atmosphere & Oce, Nanjing 210044, Jiangsu, Peoples R China
[2] Jiangsu Collaborat Innovat Ctr Atmospher Environm, Nanjing 210044, Jiangsu, Peoples R China
[3] Baylor Coll Med, Adv Technol Core, Houston, TX 77030 USA
关键词
spectroscopy; laser-induced breakdown spectroscopy; atmosphere optics; particles; heavy metal; quantitative analysis;
D O I
10.3788/LOP55.123002
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
The heavy metal in atmospheric particulates has great harm to human health, and the rapid detection of heavy metal elements therein is important. The laser-induced breakdown spectroscopy (LIES) is applied to the rapid elemental analysis of atmospheric particulates, and the results show that atmospheric particulates contain Na, Al, Si, Cu, Mg, Fe and other elements. Taking Ca clement as the reference clement, we use the internal standard method to quantitatively analyze Pb element in the atmospheric particles. The calibration curve is obtained by fitting, and it is calculated that the limit of detection of Pb clement is 34.3 X10(-6). Besides, the plasma temperature and electron number density of Pb clement arc calculated. The experimental results verify the feasibility of LIES for the qualitative and quantitative analysis of heavy metal elements in atmospheric particulates and provide experimental evidence for monitoring atmospheric heavy metal pollution.
引用
收藏
页数:7
相关论文
共 27 条
[1]   Determinants of laser-induced breakdown spectra in N2-O2 mixtures [J].
Bak, Moon Soo ;
McGann, Brendan ;
Carter, Campbell ;
Do, Hyungrok .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2016, 49 (12)
[2]  
Cremers DA, 2006, LASER-INDUCED BREAKDOWN SPECTROSCOPY (LIBS): FUNDAMENTALS AND APPLICATIONS, P1
[3]   Bioaccessibility and health risk of arsenic and heavy metals (Cd, Co, Cr, Cu, Ni, Pb, Zn and Mn) in TSP and PM2.5 in Nanjing, China [J].
Hu, Xin ;
Zhang, Yun ;
Ding, Zhuhong ;
Wang, Tijian ;
Lian, Hongzhen ;
Sun, Yuanyuan ;
Wu, Jichun .
ATMOSPHERIC ENVIRONMENT, 2012, 57 :146-152
[4]  
Hu Y, 2017, LASER OPTOELECTRONIC, V545
[5]   Synthetic musk fragrances and heavy metals in snow samples of Beijing urban area, China [J].
Hu, Zhengjun ;
Shi, Yali ;
Niu, Hongyun ;
Cai, Yaqi .
ATMOSPHERIC RESEARCH, 2012, 104 :302-305
[6]  
HUDDLESTONE RH, 1965, PLASMA DIAGNOSTIC TE, P201
[7]  
Li M, 2013, LASER OPTOELECTRONIC, V50
[8]   Laser-based investigation of the transition from droplets to nanoparticles in flame-assisted spray synthesis of functional nanoparticles [J].
Liu, Chenyang ;
Li, Shuiqing ;
Zong, Yichen ;
Yao, Qiang ;
Tse, Stephen D. .
PROCEEDINGS OF THE COMBUSTION INSTITUTE, 2017, 36 (01) :1109-1117
[9]  
Lu C P, 2011, ACTA PHYS SINICA, V60, P388
[10]   Qualitative and quantitative analysis of milk for the detection of adulteration by Laser Induced Breakdown Spectroscopy (LIBS) [J].
Moncayo, S. ;
Manzoor, S. ;
Rosales, J. D. ;
Anzano, J. ;
Caceres, J. O. .
FOOD CHEMISTRY, 2017, 232 :322-328