NOVEL CONJUNCTION OF HETERO(MACRO)CYCLES AND A PENTAMOLYBDODIPHOSPHONATE CAGE

被引：31

作者：

LOWE, MP ^{[1
]}

LOCKHART, JC ^{[1
]}

CLEGG, W ^{[1
]}

FRASER, KA ^{[1
]}

机构：

[1] UNIV NEWCASTLE UPON TYNE,DEPT CHEM,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 04期

关键词：

D O I：

10.1002/anie.199404511

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Supramolecular chemistry with polyoxometalates should be possible by linking a crown ether with a molybdophosphonate. The synthesis of the guanidinium salt of [Mo5(ZP)2O21]2− (structure shown on the right, Z = morpholinomethyl or monoaza ‐ [15] crown ‐ 5 ‐ methyl), whose solid‐state structure is influenced by hydrogen bonds, points the way to this new class of compounds. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：451 / 454

页数：4

共 20 条

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