NOVEL CONJUNCTION OF HETERO(MACRO)CYCLES AND A PENTAMOLYBDODIPHOSPHONATE CAGE

被引：31

作者：

LOWE, MP ^{[1
]}

LOCKHART, JC ^{[1
]}

CLEGG, W ^{[1
]}

FRASER, KA ^{[1
]}

机构：

[1] UNIV NEWCASTLE UPON TYNE,DEPT CHEM,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 04期

关键词：

D O I：

10.1002/anie.199404511

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Supramolecular chemistry with polyoxometalates should be possible by linking a crown ether with a molybdophosphonate. The synthesis of the guanidinium salt of [Mo5(ZP)2O21]2− (structure shown on the right, Z = morpholinomethyl or monoaza ‐ [15] crown ‐ 5 ‐ methyl), whose solid‐state structure is influenced by hydrogen bonds, points the way to this new class of compounds. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：451 / 454

页数：4

共 20 条

[1] METAL-OXIDE CHEMISTRY IN SOLUTION - THE EARLY TRANSITION-METAL POLYOXOANIONS [J].

DAY, VW ;

KLEMPERER, WG .

SCIENCE, 1985, 228 (4699) :533-541

[2] O-17 NUCLEAR MAGNETIC-RESONANCE SPECTROSCOPY OF POLYOXOMETALATES MECHANISTIC POLYOXOANION CHEMISTRY - INTRAMOLECULAR REARRANGEMENTS OF THE ALPHA-MO8O26(4-), C6H5ASMO7O25(4-), AND (C6H5AS)2MO6O24(4-) ANIONS [J].

KLEMPERER, WG ;

SCHWARTZ, C ;

WRIGHT, DA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (24) :6941-6950

[3] STABLE ORGANIC DERIVATIVES OF HETEROPOLY ANIONS, PENTAMOLYBDOBISPHOSPHONATES [J].

KWAK, W ;

POPE, MT ;

SCULLY, TF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (20) :5735-5738

[4]

Lehn J., 1990, ANGEW CHEM, V102, P1347, DOI DOI 10.1002/ANGE.19901021117

[5] PERSPECTIVES IN SUPRAMOLECULAR CHEMISTRY - FROM MOLECULAR RECOGNITION TOWARDS MOLECULAR INFORMATION-PROCESSING AND SELF-ORGANIZATION [J].

LEHN, JM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (11) :1304-1319

[6] MULTICOMPONENT POLYANIONS .44. THE STRUCTURE OF TETRAGUANIDINIUM DIHYDROGENPENTAMOLYBDODIPHOSPHATE MONOHYDRATE [J].

LYXELL, DG ;

STRANDBERG, R ;

BOSTROM, D ;

PETTERSSON, L .

ACTA CHEMICA SCANDINAVICA, 1991, 45 (07) :681-686

[7] MULTICOMPONENT POLYANIONS .42. THE STRUCTURE OF TETRAGUANIDINIUM PENTAMOLYBDODIPHENYLPHOSPHONATE [J].

LYXELL, DG ;

STRANDBERG, R .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1988, 44 :1535-1538

[8] DIRECT SYNTHESIS OF ALPHA-AMINOMETHYLPHOSPHONIC ACIDS . MANNICH-TYPE REACTIONS WITH ORTHOPHOSPHOROUS ACID [J].

MOEDRITZ.K ;

IRANI, RR .

JOURNAL OF ORGANIC CHEMISTRY, 1966, 31 (05) :1603-&

[9] MULTICOMPONENT POLYANIONS .35. A P-31 NMR-STUDY OF AQUEOUS MOLYBDOPHOSPHATES [J].

PETTERSSON, L ;

ANDERSSON, I ;

OHMAN, LO .

ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1985, 39 (01) :53-58

[10] MULTICOMPONENT POLYANIONS .39. SPECIATION IN THE AQUEOUS H+-MOO42--HPO42- SYSTEM AS DEDUCED FROM A COMBINED EMF-P-31 NMR-STUDY [J].

PETTERSSON, L ;

ANDERSSON, I ;

OHMAN, LO .

INORGANIC CHEMISTRY, 1986, 25 (26) :4726-4733

← 1 2 →