ROLE COPPER CHLORIDES IN SANDMEYER AND MEERWEIN REACTIONS

被引：31

作者：

DICKERMAN, SC

DESOUZA, DJ

JACOBSON, N

机构：

[1] Department of Chemistry, New York University, University Heights

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 03期

关键词：

D O I：

10.1021/jo01255a048

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The mechanism of the Meerwein reaction of p-chlorobenzendiazonium chloride with several monomers has been studied by determining the variation in the composition of the products of these reactions with initial concentration of cupric chloride. The results are inexplicable in terms of mechanisms for the Meerwein reaction that involve complexes of monomer with either cuprous or cupric chloride but are consistent with a three-way competition for a common intermediate, the p-chlorophenyl radical. Relative reactivities for the addition of this radical to the several monomers have also been measured. © 1969, American Chemical Society. All rights reserved.

引用

页码：710 / +

页数：1

共 30 条

[21]

MILSTEIN N, UNPUBLISHED RESULTS

[22]

NONHEBEL DC, 1957, P ROY SOC A, V247, P16

[23]

PFEIL E, 1949, LIEBIGS ANN CHEM, V565, P183

[24]

PFEIL E, 1949, LIEBIGS ANN CHEM, V562, P163