CATENATION OF 2,2'-BIS(ETHYLTHIOMETHYL)BIPHENYL WITH COPPER(I) BROMIDE

被引：4
|
作者：
TOYOTA, S [1 ]
MATSUDA, Y [1 ]
OKI, M [1 ]
AKASHI, H [1 ]
机构：
[1] OKAYAMA UNIV SCI, NAT SCI RES INST, OKAYAMA 700, JAPAN
来源：
CHEMISTRY LETTERS | 1995年 / 01期
关键词：
D O I：
10.1246/cl.1995.31
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Treatment of 2-(ethylthiomethyl)phenyllithium with copper(I) bromide afforded a polymeric coordination compound in which 2,2'-bis(ethylthiomethyl)biphenyl molecules were linked by copper(I) bromide cores. This polymeric complex dissociates on dissolution in organic solvents and reforms on recrystallization from the solution. Other copper(I) salts also gave similar compounds, when reacted with the lithium compound.
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页码：31 / 32
页数：2
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